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Bis(tetraphenylphosphonium) di-μ-iodido-bis[diiodidopalladate(II)].

Mulligan, Frank and Nichol, Gary S. and Hurst, Stephanie K. (2007) Bis(tetraphenylphosphonium) di-μ-iodido-bis[diiodidopalladate(II)]. Acta Crystallographica, Section E: Structure Reports Online, 63 (10). Sm2558/1-Sm2558/8. ISSN 1600-5368


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Publisher’s or external URL: http://dx.doi.org/10.1107/S160053680704528X


The title compound, (PPh4)2[Pd2I6], was obtained unintentionally as the product of an attempted synthesis of a tripalladium sandwich complex. The molecular dimensions are unexceptional and the Pd---Pd distance, at 3.8183 (12) A,is much too long for any Pd—Pd interaction. Pd has a typical square-planar coordination geometry and the centrosymmetric anion is essentially planar.

Item Type: Article
ID number or DOI: 10.1107/S160053680704528X
Keywords: crystal
Subjects: Q Science > QD Chemistry
NAU Depositing Author Academic Status: Faculty/Staff
Department/Unit: College of Engineering, Forestry, and Natural Science > Chemistry and Biochemistry
Date Deposited: 30 Sep 2015 05:21
URI: http://openknowledge.nau.edu/id/eprint/274

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