Mulligan, Frank and Nichol, Gary S. and Hurst, Stephanie K. (2007) Bis(tetraphenylphosphonium) di-μ-iodido-bis[diiodidopalladate(II)]. Acta Crystallographica, Section E: Structure Reports Online, 63 (10). Sm2558/1-Sm2558/8. ISSN 1600-5368
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Publisher’s or external URL: http://dx.doi.org/10.1107/S160053680704528X
Abstract
The title compound, (PPh4)2[Pd2I6], was obtained unintentionally as the product of an attempted synthesis of a tripalladium sandwich complex. The molecular dimensions are unexceptional and the Pd---Pd distance, at 3.8183 (12) A,is much too long for any Pd—Pd interaction. Pd has a typical square-planar coordination geometry and the centrosymmetric anion is essentially planar.
| Item Type: | Article |
|---|---|
| ID number or DOI: | 10.1107/S160053680704528X |
| Keywords: | crystal |
| Subjects: | Q Science > QD Chemistry |
| NAU Depositing Author Academic Status: | Faculty/Staff |
| Department/Unit: | College of Engineering, Forestry, and Natural Science > Chemistry and Biochemistry |
| Date Deposited: | 30 Sep 2015 05:21 |
| URI: | http://openknowledge.nau.edu/id/eprint/274 |
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